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http://nopr.niscpr.res.in/handle/123456789/10413| Title: | Synthesis, crystal structure and photoluminescence property of a Cd(II) framework complex [Cd(2-PTZ)2(H2O)2] {2-PTZ = 5-(2-pyridyl tetrazolate)} |
| Authors: | Singh, Sadhana Mayer, Peter Pandey, Ashutosh |
| Keywords: | Coordination chemistry;Hydrothermal synthesis;X-ray crystallography;Photoluminescence;Cadmium |
| Issue Date: | Oct-2010 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int. Cl.9 C07F3/08; C09K11/00 |
| Abstract: | A new 2D supramolecular (hydrogen bonded) Cd(II) network, [Cd(2-PTZ)2(H2O)2]n (2-PTZ = 5-(2-pyridyl) tetrazolate) has been synthesized by hydrothermal reaction and characterized by IR, and X-ray single crystal analysis. In the molecular structure of the studied complex, Cd(II) ion is six-coordinated, which is completed by two water molecules and two 2-PTZ ligands which provide two nitrogens from the two tetrazolyl groups and two nitrogen atoms from pyridyl rings. The mononuclear units are assembled by intermolecular hydrogen bonding to generate two-dimensional sheets. Photoluminescence spectrum of the polymer complex exhibits strong blue emission at λmax = 439 nm in the solid state at room temperature. |
| Page(s): | 1345-1348 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.49A(10) [October 2010] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 49A(10) 1345-1348.pdf | 206.25 kB | Adobe PDF | View/Open |
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