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http://nopr.niscpr.res.in/handle/123456789/1207| Title: | Influence of apolar aprotic solvents on proton transfer equilibrium between m-/o-chlorobenzoic acids and the carbinol base of crystal violet: A chemometric analysis |
| Authors: | Shrivastava, Ruchi Mishra, Sangeeta Sengupta, Susanta K |
| Issue Date: | Jun-2007 |
| Publisher: | CSIR |
| Abstract: | A chemometric analysis of equilibrium results for apolar aprotic solvent effects on proton transfer between m-/o-chlorobenzoic acids and crystal violet carbinol base using Koppel-Palm’s approach shows that the total solvent effect is contributed mainly by dispersion and dipolar/electrostatic interactions in approximately 7:4 ratio. A parallel study with m- and o-fluorobenzoic acids but under conditions favouring acid-acid anion homoconjugation reflects the role of homoconjugated complexed acids in substantially modifying the detailed pattern of solvent effects. |
| Page(s): | 933-936 |
| ISSN: | 0376-4710 |
| Appears in Collections: | IJC-A Vol.46A(06) [June 2007] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 46A(6) (2007) 933-936.pdf | 70.85 kB | Adobe PDF | View/Open |
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