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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Jain, Rajeev | - |
| dc.contributor.author | Yadav, Ramji Lal | - |
| dc.contributor.author | Karaiya, Shrinarayan | - |
| dc.contributor.author | Arya, Virendra K. | - |
| dc.date.accessioned | 2011-08-26T04:24:57Z | - |
| dc.date.available | 2011-08-26T04:24:57Z | - |
| dc.date.issued | 2011-09 | - |
| dc.identifier.issn | 0975-1084 (Online); 0022-4456 (Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/12600 | - |
| dc.description | 767-772 | en_US |
| dc.description.abstract | Electrochemical behaviour of 2-[4'-(substituted)
sulphonamoyl- phenyl]hydrazono ethyl-2-cyanoethanoate (SHEC) in
Britton-Robinson buffers (pH 2.05-10.5) showed that all
SHECs gave a single reduction wave at dropping mercury electrode.
Cyclic voltammograms exhibited a well defined
irreversible cathodic peak at glassy carbon electrode. On the basis of DC,
differential pulse polarography and cyclic voltammetry,
a reaction mechanism has been suggested. Kinetic parameters [charge
transfer coefficient ( na), forward rate constant (k°f,h) and
diffusion-coefficient] have been calculated by polarographic and cyclic
voltammetric methods. A plausible mechanism has also
been suggested on the basis of protons involved in rate determining step
and number of electrons
involved in reduction process. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | JSIR Vol.70(09) [September 2011] | en_US |
| dc.subject | Cyclic voltammetry | en_US |
| dc.subject | DC polarography (DCP) | en_US |
| dc.subject | Differential pulse polarography (DPP) | en_US |
| dc.subject | 2-[4'-(Substituted)sulphonamoylphenyl]hydrazono ethyl-2-cyanoethanoate (SHEC) | en_US |
| dc.title | Synthesis and electrochemical behaviour of 2-[4'-(substituted)sulphonamoylphenyl]hydrazono ethyl-2-cyanoethanoate | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | JSIR Vol.70(09) [September 2011] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| JSIR 70(9) 767-772.pdf | 125.01 kB | Adobe PDF | View/Open |
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