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http://nopr.niscpr.res.in/handle/123456789/14364| Title: | Synthesis and characterisation of arylazoimidazolium iodide and tetraiodocadmium(II) compounds |
| Authors: | Mallick, D Saha, R Sarker, K K Datta, P Sinha, C |
| Keywords: | Coordination compounds;Inorganic-organic hybrids;Cadmium;Dialkyl-arylazoimidazolium salts;Arylazoimidazolium salts;Iodometallates;X-ray structures;Density functional calculations |
| Issue Date: | Jul-2012 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Sixteen new inorganic-organic hybrid compounds of 1,3-dialkyl-2-(arylazo)imidazolium, [RaaiR/R//]+ (R, alkyl group), and I- or [CdI4]2- as counter ion are synthesized and characterized by spectroscopic (IR, UV-vis, 1H NMR) techniques. The single crystal X-ray diffraction studies of representative compounds, viz., 1,3-dimethyl-2-(p-tolylazo)imidazolium iodide [MeaaiMe2+]I- and bis- [1-methyl-3-benzyl-2-(p-tolylazo)imidazolium]tetraiodocadmium(II) [Meaai(Me)CH2Ph+]2 [CdI4]2-, have confirmed the proposed structures. DFT computation has been used to explain the electronic structure and the electronic spectra of the compounds. |
| Page(s): | 917-926 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.51A(07) [July 2012] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 51A(7) 917-926.pdf | 363.83 kB | Adobe PDF | View/Open |
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