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http://nopr.niscpr.res.in/handle/123456789/15488| Title: | A single step synthesis of some cyanonitrosyl {CrNO}5 complexes of chromium(I) involving multi-functional ligands directly from chromate(VI) in aqueous-aerobic medium |
| Authors: | Maurya, R C Thakur, S K Batalia, S |
| Issue Date: | Aug-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Novel mixed-ligand cyanonitrosyl complexes of chromium(I), formed by interaction of tetracyanonitrosylchromate(I) anion. [Cr(NO)(CN)4]2 with 8-hydroxyquinoline (8-HQ), benzothiazole (BZT), imidazole (IDL), methyl benzothiazole (MBZT) and pheniramine maleate (PHM) are described. The resulting mixed-ligand complexes, which have been characterized by elemental analyses, molar conductances, magnetic measurements, electron spin resonance, infrared and electronic spectral studies, have the compositions [Cr(NO)(CN)2(L)2 (H2O)], where L= BZT. MBZT or IDL and [Cr(NO)(CN)2 (L-L)(H2O)] where L-L = 8-HQ or PHM. A cis- octahedral structure has been proposed for these complexes. |
| Page(s): | 867-870 |
| Appears in Collections: | IJC-A Vol.39A(08) [August 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(8) 867-870.pdf | 891.61 kB | Adobe PDF | View/Open |
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