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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Vasisht, S K | - |
| dc.contributor.author | Kaushal, Jyotsna | - |
| dc.date.accessioned | 2012-12-31T20:27:23Z | - |
| dc.date.available | 2012-12-31T20:27:23Z | - |
| dc.date.issued | 2000-08 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/15491 | - |
| dc.description | 863-866 | en_US |
| dc.description.abstract | Reactions of lithium tris(trimethylsilyl)hydrazine (1) with ECl3 (E= AI, Fe) and Me2SnCI2 show that (1) undergoes substitution reaction to give stable silylated metallahydrazines, (Me3Si)2N-N(SiMe3)AICI2 and (Me3Si)2N-N (SiMe3)2 SnC1(Me2), whereas, FeCI3 acts as an oxidant to give Me3SiN=NSiMe3 . However, EX4 (E = Sn, Ti and X= CI, I) and SbCI5 provide disubstituted products [(Me3Si)2N-N(SiMe3)2EXn-2. SnCI2, gives a two coordinated Sn(II) derivative Sn[(Me3Si) 3N2] 2. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.39A(08) [August 2000] | en_US |
| dc.title | Silyl - nitrogen compounds: Part (XI)Synthesis of silylated metallahydrazines | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.39A(08) [August 2000] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(8) 863-866.pdf | 696.91 kB | Adobe PDF | View/Open |
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