Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/15492| Title: | Cleavage of Co-C bond in allyl cobaloximes with arenesulphenyl chloride |
| Authors: | Gupta, B D Dixit, Vandana Singh, Veena Kanth, V Vijai |
| Issue Date: | Aug-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Arenesulphenyl chlorides (ArSCI; Ar = Ph, C6Cl5,
2,4(N02)2 C6H3) are reacted with allylcobaloximes,
RCo(dmgH)2Py (R= allyl), under thermal and photochemical conditions
to obtain the corresponding sulphides as the major organic products. -Pinenyl
cobaloxime forms the ring opened product as well. The homolytic as well as
heterolytic cleavage of the Co-C bond is considered. |
| Page(s): | 830-834 |
| Appears in Collections: | IJC-A Vol.39A(08) [August 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(8) 830-834.pdf | 1.04 MB | Adobe PDF | View/Open |
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