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http://nopr.niscpr.res.in/handle/123456789/15496| Title: | Alcoholate derivatives of bimetallic [Sn(IV),Al(III)] -μ-oxoisopropoxy acetate and -μ-oxoisopropoxide |
| Authors: | Deepali Bansal, A Aggarwal, S Narula, A K |
| Issue Date: | Aug-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Alcoholysis of bimetallic-μ-oxoisopropoxide Bu2Sn(OAc)OAI(OPri)2[I] and Bu2SnO2AI2 (OPri)4 [II] has been carried out with cyclic alcohols, viz., cyclopentanol (CyPH), cyclohexanol (CyHxH) and cycloheptanol (CyHpH). The isopropoxy replacement reactions of these compounds I and II with cyclic alcohol yield compounds of the type Bu2Sn(OAc)OAI(OPri)2-n Ln (where n=1 or 2) and Bu2Sn(OAc)OAI(OPri)4-n Ln (where n= 1 to 3) (L= deprotonated anion of cyclic alcohol). The novel compounds have been characterised on the bas is of IR. 1H NMR, 13C NMR, 119Sn NMR and 27 AI NMR. |
| Page(s): | 883-885 |
| Appears in Collections: | IJC-A Vol.39A(08) [August 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(8) 883-885.pdf | 680.41 kB | Adobe PDF | View/Open |
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