Synthesis and characterization of toluene- 3,4-dithiolatoantimony(III) diorganodithiophosphates

Abstract

Displacement reactions of toluene-3,4-dithiolatoantimony(III) chloride with sodium diorganodithiophosphates in 1:1 molar ratios in anhydrous benzene yield mixed toluene-3,4- dithiolatoantimony(III) diorganodithiophosphates of the type SC₆H₃(CH₃)SSbS₂P(OR)₂ (where R = Prⁿ, Prⁱ, Buⁿ and Buⁱ).

<span style="font-size:14.0pt;font-family:" times="" new="" roman";mso-fareast-font-family:="" "times="" roman";mso-ansi-language:en-us;mso-fareast-language:en-us;="" mso-bidi-language:ar-sa"="">These derivatives have been characterised by elemental analysis <span style="font-size:14.0pt;font-family:Arial;mso-fareast-font-family: " times="" new="" roman";mso-ansi-language:en-us;mso-fareast-language:en-us;="" mso-bidi-language:ar-sa"="">(C, <span style="font-size:14.0pt;font-family: " times="" new="" roman";mso-fareast-font-family:"times="" roman";mso-ansi-language:="" en-us;mso-fareast-language:en-us;mso-bidi-language:ar-sa"="">H, Sb and S), as well as IR , NMR (¹H and ³¹P) spectral studies.</span></span></span>