Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/15597| Title: | Kinetics and mechanism of oxidation of nitrites with Bi(V) in HCIO4-HF mixture |
| Authors: | Roy, Ramesh Kumar Mishra, Prem Mohan Jha, Ashok Kumar Jha, C S |
| Issue Date: | Feb-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Kinetics of oxidation of nitrite ion (NO2-) wilh Bi(V) nuoride complex have been investigated in HCIO4-HF mixture. The reaction is first order in each reactant. Hydrogen ion (H+) and ionic strength have inverse effect on the reaction rate. The effect of HF and added nuoride ion (F) are found to be negligible. The mode of electron transference from the substrate (NO2) to the oxidant Bi(V) has been indicated via a bridged outer-sphere mechanism. |
| Page(s): | 187-189 |
| Appears in Collections: | IJC-A Vol.38A(02) [February 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(2) 187-189.pdf | 572.71 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.