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http://nopr.niscpr.res.in/handle/123456789/15600| Title: | Rhodium(III) complexes containing acetylacetonate and mono- or bidentate ligands |
| Authors: | Sarkhel, Prashanta Paul, Bipul C Poddar, Raj K |
| Issue Date: | Feb-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A Rh(III) complex, viz., [RhCl2(acac)(acacH)] (acacH = acetylacetone) has been isolated in high yield by the reaction of RhCl3, with acacH. The compound is a convenient starting material for the synthesis of a variety of Rh(III) complexes, viz., [RhX2(acac)L2] (X = Cl or Br; L = PPh3, AsPh3 or py), [RhX2(acac)(L-L)] (X = CI or Br; L-L = bipy or phen) and M2[RhCI4(acac)] (M = NMe4 or Cs). These compounds have been characterised using analytical data, physico-chemical, spectroscopic and electrochemical techniques. |
| Page(s): | 150-155 |
| Appears in Collections: | IJC-A Vol.38A(02) [February 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(2) 150-155.pdf | 1.34 MB | Adobe PDF | View/Open |
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