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http://nopr.niscpr.res.in/handle/123456789/15647| Title: | Synthesis, characterization and electrochemistry of unsymmetrical macrocyclic organocobalt complexes |
| Authors: | Reddy, K Hussain Reddy, M Radhakrishna Raju, K Mohana |
| Issue Date: | Mar-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Macrocyclic cobalt complexes with varying ring sizes have been prepared by template synthesis using bis(benzil)ethylene diimine and different diamines viz. 1,4-diaminobutane, 1,2-diaminobenzene and 3,4-diaminotoluene. These complexes have been alkylated using CH3I and/or C2H5Br in the presence of pyridine and/or imidazole to obtain corresponding macrocyclic organocobalt complexes. The alkylated derivatives have been characterized by elemental analysis, conductivity measurements, magnetic susceptibility measurments, electronic and infrared spectral data. The CV results suggest that all the alkyl cobalt(III) complexes undergo two sequential one electron reductions, Co(III)→ Co(II) and Co(II) → Co(I). |
| Page(s): | 299-302 |
| Appears in Collections: | IJC-A Vol.38A(03) [March 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(3) 299-302.pdf | 885.54 kB | Adobe PDF | View/Open |
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