Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/15704| Title: | Synthesis and X-ray crystal structure of nBu2SnC12. (C6H5N=CHC5H4N-2) |
| Authors: | Baul, Swarnali Basu Baul, Tushar S Basu Tiekink, Edward R T |
| Issue Date: | May-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Diorganotin (IV) dichloride complex of
the composition nBu2SnCl2. (C6H5N=CHC5H4N-2) has been isolated from the reaction
of nBu2SnCl2 and the ligand C6H5N=CHC5H4N-2 in CH2Cl2.
The crystal structure of the title compound
has been determined.
The crystal belongs to the orthorhombic
space group P212121 with the following
unit cell dimensions for C20H28Cl2N2Sn (M = 486.1 ):
a = 12.098(2) Å, b = 1 8.830(2) Å, c = 9.731 (2) Å,  = β =  = 90°, v = 2216.7(5) Å3 , Z= 4, Dc = 1.456 g cm-1 , μ =
13.98 cm-1, R =0.036, Rw =0.033 for 1857 reflections with 1 ≥ 3.0 σ (1).
The structure of the organotin compound is molecular and features an octahedral
tin atom which is coordinated by two butyl groups, two chloride atoms and two
chemically non-equivalent nitrogen donor atoms in the ligand. |
| Page(s): | 501-505 |
| Appears in Collections: | IJC-A Vol.38A(05) [May 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(5) 501-505.pdf | 2.25 MB | Adobe PDF | View/Open |
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