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http://nopr.niscpr.res.in/handle/123456789/15719| Title: | Kinetics and mechanism of the vapour phase ammoximation of cyclohexanone by nitric oxide and ammonia over Al2O3.SiO2 catalyst |
| Authors: | Prasad, R Vashisht, Seema |
| Issue Date: | May-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The kinetics of ammoximation of cyclohexanone by nitric oxide and ammonia, in vapour phase have been investigated over Al2O3.SiO2 catalyst in a differential flow reactor between 150 and 250°C. The rate equation r = k1 pc pa has been deduced which represents the data most satisfactorily for the conversion of cyclohexanone to caprolactam. A tentative reaction mechanism has been proposed. |
| Page(s): | 446-452 |
| Appears in Collections: | IJC-A Vol.38A(05) [May 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(5) 446-452.pdf | 1.12 MB | Adobe PDF | View/Open |
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