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http://nopr.niscpr.res.in/handle/123456789/15760| Title: | Synthesis, structure and separation of a new chiral metal cluster (μ3-S)FeCoMo(CO)8 {C5H4C(O)C6H4C(O)OCH3-4} on an amylopectin tris-(phenylcarbamate) chiral column by HPLC |
| Authors: | Zhou, Zhigiang Ding, Errun Hou, Jingguo Chen, Liren |
| Issue Date: | May-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Preparation of amylopectin tris(phenylcarbamate) (ATP) chiral stationary phases (CSPs) coated on small-particle (5μm, 120Å) spherical silica support is reported. A new chiral tetrahedral cluster FeCoMo(μ3-S) (CO)8{C5H4C(O)C6H4C(O)OCH3-4) (2) has been synthesized by the thermal reaction of the precursor (μ-S)FeCO2 (CO)9 with functionally substituted cyclopentadienyl tricarbonyl metal anion [Mo(CO)3C5H4C(O)CH3] and it has been resolved on the amylopectin tris (phenylcarbamate) chiral stationary phase. |
| Page(s): | 411-415 |
| Appears in Collections: | IJC-A Vol.38A(05) [May 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(5) 411-415.pdf | 1.02 MB | Adobe PDF | View/Open |
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