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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ayoko, G. Adefikayo | - |
| dc.contributor.author | Iyun, J. Femi | - |
| dc.contributor.author | Faruk, Yusuf U. | - |
| dc.date.accessioned | 2013-01-18T17:00:23Z | - |
| dc.date.available | 2013-01-18T17:00:23Z | - |
| dc.date.issued | 1999-05 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/15763 | - |
| dc.description | 458-461 | en_US |
| dc.description.abstract | The kinetics of the oxidation of nitrous acid by Fe(LL)33+ (LL = 2,2' -bipyridine or 1,10 phenanthroline) has been studied in aqueous acidic medium. In the acid range [H+] = 0.20-2.00 mol dm-3,the rate conforms to the equation : Rate = 2k[Fe(LL)33+][HNO2 where k = 0.38 and 0.24 mol-1 dm3 s-1 I at 25.0°C for the reactions with LL = 1,10 phenanthroltne and 2,2’ -bipyridine respectively. The reactions are thought to occur by the outer sphere mechanism based on (i) substitution inertness of the oxidants, (ii) excellent Marcus-type correlation and (iii ) low ion-pair formation constants. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.38A(05) [May 1999] | en_US |
| dc.title | Oxidation of nitrous acid by tris( diimine) iron (III) complexes | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.38A(05) [May 1999] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(5) 458-461.pdf | 881.16 kB | Adobe PDF | View/Open |
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