Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/15764
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dc.contributor.authorLobana, Tarlok S-
dc.contributor.authorVerma, Renu-
dc.date.accessioned2013-01-18T17:01:45Z-
dc.date.available2013-01-18T17:01:45Z-
dc.date.issued1999-06-
dc.identifier.urihttp://hdl.handle.net/123456789/15764-
dc.description592-595en_US
dc.description.abstractReactions of palladium(II)/platinum(II) chlorides with sodium salts of pyridine-2-thione (Na+C5H4NS-) or l-hydroxypyridine-2- thione(Na+C5H4NOS-) yield products of composition, Pd(C5H4NS)2 (1), Pd(C5H4NOS)2 (2) and Pt(C5H4NOS)2 (3). Reactions of 1-3 with triphenyl- phosphine gave Pd(C5H4NS)2 (PPh3)2 (4), Pd(C5H4NOS)2 (PPh3) (5) and Pt(C5H4NOS)2 (PPh3)2 (6). All the complexes have been characterised by analytical data, IR, far IR and multinuclear (1H, 13C, 31P) NMR spectroscopy. It is observed that whereas 1 and 2 show one type of isomer, 3 exhibits cis-trans isomerism in the ratio of 1:2.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.38A(06) [June 1999]en_US
dc.titleMetal-heterocyclic thione interactions. 11. Preparation and NMR spectroscopy of bis(pyridine-2-thiolato- or 1-oxopyridine-2- thione) palladium(II)/platinum(II) and their triphenylphosphine complexesen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.38A(06) [June 1999]

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