Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/15787| Title: | Physicochemical studies of 2-propanol in some micellar solutions |
| Authors: | Yadav, Satyender K Kumar, Ashok Yadav, O P` |
| Issue Date: | Jun-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Conductance values of sodium dodecyl sulphate
and dodecyl trimethyl ammonium bromide have been measured in aqueous and
2-propanol+water solutions. The measurements are carried out at 298.15, 308.15
and 318.15 K. From conductivity data the values of critical micelle
concentration and counterion association constant ( )
are determined. The observed thermodynamic data
reveals that micellisation process is favoured both energetically as well as
by entropy gain. 1H NMR data of solutions indicate that whereas
2-propanol is solubilised in the interior of SDS micelles, the penetration of
2-propanol into DTAB micelles is comparatively weak. |
| Page(s): | 529-532 |
| Appears in Collections: | IJC-A Vol.38A(06) [June 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(6) 529-532.pdf | 780.63 kB | Adobe PDF | View/Open |
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)
are determined. The observed thermodynamic data
reveals that micellisation process is favoured both energetically as w