Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/15805| Title: | Interaction of some azole bases with [Pt(dien)Br]+ : Conductometric and spectrophotometric studies |
| Authors: | Saha, Basudeb Ray, Monojit Banerjee, Pradyot |
| Issue Date: | Jul-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Kinetics of the reaction of four azole bases (e.g., imidazole, benzimidazole, pyrazole and triazole) with [Pt(dien)Br] + (dien = diethylenetriamine) has been studied in aqueous solution (27°C) by conductometric and spectrophotometric methods. The reactions follow normal square-planar substitution having the rate law Linder pseudo-first order condition, kobs = k1 + k2 [azole base]. The aged solution of [Pt(dien)Br] + shows biphasic reaction traces due to formation of the reactive [Pt(dien)(H2O)]2+ in solution. The adducts formed with these bases have been isolated and characterised. |
| Page(s): | 656-659 |
| Appears in Collections: | IJC-A Vol.38A(07) [July 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(7) 656-659.pdf | 938.52 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.