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http://nopr.niscpr.res.in/handle/123456789/15825Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Joseph, Trissa | - |
| dc.contributor.author | Sajanikumari, C S | - |
| dc.contributor.author | Deshpande, S S | - |
| dc.contributor.author | Gopinathan, Sarada | - |
| dc.date.accessioned | 2013-01-23T19:07:03Z | - |
| dc.date.available | 2013-01-23T19:07:03Z | - |
| dc.date.issued | 1999-08 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/15825 | - |
| dc.description | 792-796 | en_US |
| dc.description.abstract | Salen and substituted salen schiff base complexes of cobalt(II) have been synthesized. These Complexes have been encapsulated in the supercages of Na-Y zeolite employing flexible ligand method. The neat as well as the zeolite encapsulated complexes have been characterised by XRD, FTIR and UV-vis spectroscopy. Aerial oxidation of p-cresol using these catalysts in presence of a base affords p-hydroxybenzaldehyde (PHBA) in good yield. Among the catalysts studied, cobalt-chlorosalen-Y gives almost 100% conversion of p-cresol with 97% selectivity towards PHBA with a turnover frequency of 1049/h. The spent encapsulated catalysts retain their identity after the oxidation reactions as seen from their IR spectra. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.38A(08) [August 1999] | en_US |
| dc.title | Oxidation of p-cresol catalyzed by neat and zeolite encapsulated cobalt salen complexes | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.38A(08) [August 1999] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(8) 792-796.pdf | 1.03 MB | Adobe PDF | View/Open |
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