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http://nopr.niscpr.res.in/handle/123456789/15833| Title: | Synthesis of some manganese(O) cyanonitrosyl derivatives containing heterocyclic nitrogen donors |
| Authors: | Maurya, R C Pillai, V Singh, T |
| Issue Date: | Aug-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Novel mixed -ligand cyanonitrosyl complexes of Mn(O), obtained from the interaction of tetracyanodinitrosylmagante(O) anion, [Mn(NO)2(CN) 4]2with 2-hydroxymethylpyridine (2-HMP), 3-hydroxymethylpyridine (3-HMP), 2—aminopyridine (2- AP), 2-(2' -aminoethyl)pyriidine(2 -AEP), quinaldic acid (QD), nicotinic acid (NA) and methyl nicotinate (MNIC) are described . The products have the general formula [Mn(NO)2(CN)2(L)2] (where L-L=QD, NA, 2-AEP, 2-AP or MNIC) . Octahedral structures have been suggested for these complexes. Mn(0) has a low-spin {Mn(NO)2}7 electron configuration1 in these complexes. |
| Page(s): | 829-832 |
| Appears in Collections: | IJC-A Vol.38A(08) [August 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(8) 829-832.pdf | 933.09 kB | Adobe PDF | View/Open |
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