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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Anand, B N | - |
| dc.contributor.author | Bains, Rajwant | - |
| dc.contributor.author | Venugopalan, P | - |
| dc.date.accessioned | 2013-01-24T17:13:38Z | - |
| dc.date.available | 2013-01-24T17:13:38Z | - |
| dc.date.issued | 1999-09 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/15843 | - |
| dc.description | 874-879 | en_US |
| dc.description.abstract | Reaction of
pentachlorophosphorane with o-Aminophenol
in 1:2 mole ratio under controlled temperature conditions yields a
spirobicyclic phosphorane (1) in
which a five-membered ring with oxygen and nitrogen bonded to a pentavalent phosphorus.
However, at higher temperatures of the reaction, a benzoxazaphosphole (2)
is isolated which crystallises in a
triclinic system,
space group P‾1 and has structural
parameters of a =
8.2932 (8) Å, b =
9.4138(9 ) Å, c =10.4382(10) Å and  =96.073(2)°,
β= 108.303(1)°,  =112.785(1)°.
R1 = 0.0610, wR2 = 0.1178 for 1574 reflections [1> 2 σ (I)]. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.38A(09) [September 1999] | en_US |
| dc.title | Synthesis and characterization of spirobicyclic hypervalent phosphorus species : X-ray structural study of a dibenzoxazaphosphole | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.38A(09) [September 1999] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(9) 874-879.pdf | 2.1 MB | Adobe PDF | View/Open |
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