Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/15897
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dc.contributor.authorMeng, Fa-Yan-
dc.contributor.authorYu, Sheng-Rong-
dc.contributor.authorMa, Lin-
dc.contributor.authorLin, Cui-Wu-
dc.date.accessioned2013-02-05T09:45:10Z-
dc.date.available2013-02-05T09:45:10Z-
dc.date.issued2013-02-05T09:45:10Z-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/15897-
dc.description192-199en_US
dc.description.abstractA new organic complex salt based on chlorogenic acid with 1,10-phenanthroline has been synthesized and characterized. The complex adopts 1:1 stoichiometry in the solid state. The proton transfer occurs from the carboxyl oxygen to the aromatic nitrogen atom to form the salt. The Hphen molecule individually occupies the pseudo-tetragonum that is formed with chlorogenic acid. The self-assembly of the compound in solid state is caused by a hydrogen-bonding interaction. The interaction of the organic complex salt with bovine serum albumin molecules has been studied by fluorescence spectroscopy. The bimolecular quenching constant, apparent quenching constant and number of binding sites have been obtained by fluorescence quenching and the binding distance calculated according to Foster’s non-radioactive energy transfer theory. The corresponding thermodynamic parameters ΔH, ΔG and ΔS have also been calculated. The conformational changes of BSA have been observed from synchronous fluorescence spectra.en_US
dc.language.isoen_USen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.52A(02) [February 2013]en_US
dc.subjectOrganic complex saltsen_US
dc.subjectChlorogenic aciden_US
dc.subjectFluorescence spectroscopyen_US
dc.subjectBovine serum albuminen_US
dc.titleSynthesis, crystal structure and spectroscopic investigations on organic complex salt and its interaction with bovine serum albuminen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.52A(02) [February 2013]

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