Synthesis and Electrochemical behavior of 1-Ethyl-2-[4’- <span style="font-size:15.0pt;font-family:"Times New Roman";mso-fareast-font-family: "Times New Roman";mso-ansi-language:EN-IN;mso-fareast-language:EN-IN; mso-bidi-language:AR-SA">sulphonamoylphenyl] hydrazone-3-oxotanoates</span>

Abstract

<span style="font-size:9.0pt;font-family:" times="" new="" roman";="" mso-fareast-font-family:"times="" roman";mso-ansi-language:en-in;mso-fareast-language:="" en-in;mso-bidi-language:ar-sa"="">Electrochemical behaviour of 1-Ethyl-2-[4’-sulphonamoylphenyl] hydrazone-3-oxobutanoates (ESPHO) have been studies in the Britton-Robinson buffers of the 2.5-12.0 at dropping mercury electrode and glassy carbon electrode. This compound gives one four-electron wave corresponding to the reduction of hydrazono group at mercury electrode. On the basis of direct current polarographic, pulse polarographic, cyclic voltammetry and controlled potential electrolysis, IR, mass, and ^{<span style="font-size:5.5pt;font-family:" times="" new="" roman";mso-fareast-font-family:="" "times="" roman";mso-ansi-language:en-in;mso-fareast-language:en-in;="" mso-bidi-language:ar-sa"="">1</span>}<span style="font-size:9.0pt;font-family: " times="" new="" roman";mso-fareast-font-family:"times="" roman";mso-ansi-language:="" en-in;mso-fareast-language:en-in;mso-bidi-language:ar-sa"="">H NMR spectral studied and product identification, a reaction mechanism is suggested to account for the reduction mechanism. </span></span>