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http://nopr.niscpr.res.in/handle/123456789/16093| Title: | Effect of oxidants on olefin epoxidation catalyzed by a new nickel(II)-schiff base complex |
| Authors: | Chatterjee, Debabrata Mukherjee, Sanghamitra Mitra, Anannya |
| Issue Date: | Nov-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A new schiff base complex of nickel(II), NiL ( where H2L= N-(2- hydroxyphenyl) salicyldiimine} has been prepared in good yield by direct interaction of schiff base ligand, H2L and NiCI2 and characterized by physico-chemical analysis. Efficiency of the NiL complex towards catalysing epoxidation of olefins in presence of various oxidants vi z., NaOCI , KHSO5, H2O2 ,pyridine N-oxide (PyO), t-BuOOH, etc. , has been examined and it is found that the NiL complex can effectively catalyze the epoxidation of olefins in presence of NaOCI and KHSO5. |
| Page(s): | 1177-1180 |
| Appears in Collections: | IJC-A Vol.38A(11) [November 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(11) 1177-1180.pdf | 828.39 kB | Adobe PDF | View/Open |
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