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http://nopr.niscpr.res.in/handle/123456789/16103| Title: | First example of a double stranded helicate with square-planar coordination for the metal |
| Authors: | Zimmer, Marc Tocher, Derek A Patra, Goutam K Naskar, Jnan P Datta, Dipankar |
| Issue Date: | Nov-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reaction of dichlorobis(benzildihydrazone)Ni(II) with biacetylmonoxime in 1:4 molar proportion generates diamagnetic Ni2L2 where LH2 (H = dissociable oximato proton) is HO-N=C(CH3)-C(CH3)=N-N=C(C6H5)-C(C6H5)=N-N=C(CH3)-C(CH3)=N-OH. Our molecular mechanics calculations show that Ni2L2 is an unprecedented double stranded homotopic helicate with the metal ion having a square-planar N4 coordination. |
| Page(s): | 1087-1091 |
| Appears in Collections: | IJC-A Vol.38A(11) [November 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(11) 1087-1091.pdf | 1.96 MB | Adobe PDF | View/Open |
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