Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/16159| Title: | Copper(II) complexes with bis thiazole based ligands: Spectral, cyclic voltammetric and EPR studies |
| Authors: | Das, Sanjib Kumar Mathur, Pavan |
| Issue Date: | Dec-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A series of complexes with stoichiometry corresponding to [CuLX2] has been synthesised, where L is a potentially tridentate ligand carrying pendant benzothiozolyl groups and X = CIO4- ,Cl-, NO3-, CH3COO- and HCOO-. EPR spectra of the complexes examined as a frozen DMF solution reveal a distorted tetragonal geometry. The visible band energy for these copper(II) complexes is found to fall in the range observed for N2O2 type donor environment, while the plot of the reduction potential versus d-d band energy indicates that increasing covalency leads to a decrease in dx2-y2orbital energy and a concomitant anodic shift. |
| Page(s): | 1277-1282 |
| Appears in Collections: | IJC-A Vol.38A(12) [December 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(12) 1277-1282.pdf | 1.17 MB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.