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http://nopr.niscpr.res.in/handle/123456789/16178| Title: | Ring closure reaction of 4-tert-butyl-4- penten-1-ol with electrophilic reagents |
| Authors: | Mihailovic, M Lj Gojkovic, S Milosavljevic, S Konstantinovic, S |
| Issue Date: | Jan-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The reaction of 4-tert-butyl-4-penten-1-ol 3 with some electrophilic reagents (such as mineral acids, mercuric acetate, peracids) has been investigated. It is found that in the acid (H2SO4)catalysed reaction of 3, the products of 1,2- methyl rearrangement are produced. The oxymercuration/demercuration reaction of 3 and its reaction with meta-chloroperbenzoic acid afford in high yields exclusively Markovnikov-type products. |
| Page(s): | 101-105 |
| Appears in Collections: | IJC-B Vol.38B(01) [January 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(1) 101-105.pdf | 728.14 kB | Adobe PDF | View/Open |
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