Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/16239Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Nandanan, E | - |
| dc.contributor.author | Phukan, Prodeep | - |
| dc.contributor.author | Sudalai, A | - |
| dc.date.accessioned | 2013-03-04T18:07:12Z | - |
| dc.date.available | 2013-03-04T18:07:12Z | - |
| dc.date.issued | 1999-03 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/16239 | - |
| dc.description | 283-286 | en_US |
| dc.description.abstract | The reaction of 4(S)-carbethoxy-5(R)-phenyl-1,3,2-dioxathiolane-2,2-dioxide 4 with MgBr2.Et2O readily proceed regio- and stereoselectively at the benzylic position to afford the desired bromohydrin 5 in excellent yield which led to an improved process for the synthesis of (2R, 3S)-( -)-N-benzoyl-3-phenylisoserine ethyl ester 8 (taxol C13 side chain) in excellent yield and optical purity. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-B Vol.38B(03) [March 1999] | en_US |
| dc.title | Regio and stereoselective opening of chiral cyclic sulfates with MgBr2-Et2O: A practical strategy for the synthesis of (2R,3S)-(-)-N-benzoyl-3-phenylisoserine ethyl ester (taxol side chain) | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-B Vol.38B(03) [March 1999] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(3) 283-286.pdf | 913.21 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.