Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/16432| Title: | Oxidation of olefins and hydrazones by anodically in situ generated manganese (III) acetate |
| Authors: | Dubey, Shipra Singh, Dan Misra, R A |
| Issue Date: | May-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The oxidation of
olefins and hydrazones of carbonyl compounds has been performed by using in
situ anodically generated milder oxidant Mn(III) acetate at Pt electrode in
acetic acid. The oxidation of acyclic olefins leads to the formation of 1,2-diacetate
while in the case of cyclic olefin it results in the formation of  -lactone
ring onto double bond. Further, intermolecular carbolactonization of olefins
has been achieved using more reactive carboxylic acid substrate i.e. ethyl
hydrogen malonate at room temperature under the similar reaction conditions.
Mn(III) acetate oxidation of hydrazones of carbonyl compounds leads to its
fragmentation products. |
| Page(s): | 548-552 |
| Appears in Collections: | IJC-B Vol.38B(05) [May 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(5) 548-552.pdf | 968.96 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.