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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Soman, Shubhangi S | - |
| dc.date.accessioned | 2013-03-23T12:55:16Z | - |
| dc.date.available | 2013-03-23T12:55:16Z | - |
| dc.date.issued | 1999-05 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/16438 | - |
| dc.description | 542-544 | en_US |
| dc.description.abstract | Dimethylacetylenedicarboxylate on condensation with 7-hydroxy-4-ethylbenzopyran-2[H]-one 1 furnishes an inseparable cis-trans mixture of 4-methyl-7-(dimethylethene-dicarboxylate)oxybenzopyran-2[H]-one 2. It is then hydrolysed to give corresponding cis-trans mixture of acids 3, which are cyclised with cone. H2SO4 to give 2,10-dioxo-4- methyl-2[H], 10[H]-benzo[1,2-b:5,6-b']dipyran-8-carboxylic acid 4. Esterification of 4 with dimethyl sulphate gives the corresponding methyl ester 5. Similarly 2,6-dioxo-4,10-dimethyl-2[H], 6[H]benzo[1,2-b:4,5-b']dipyran-8-carboxylic acid 10 and 2,5-dioxo-4-methyl of the above carboxylic acids 2[H], 5[H]-benzo[1,2-b:3,4-b']dipyran-7-carboxylic acid 15 are prepared from 7-hydroxy-4,8-dimethylbenzopyran-2[H]-one 6 and 6-hydroxy-4-methylbenzopyran 2[H]-one 11 . | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-B Vol.38B(05) [May 1999] | en_US |
| dc.title | Synthesis of some 2,10-dioxo-4-methyl-2[H], 10[H]benzo[1,2-b:5,6-b']dipyran-8-carboxylic acids | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-B Vol.38B(05) [May 1999] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(5) 542-544.pdf | 623.1 kB | Adobe PDF | View/Open |
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