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http://nopr.niscpr.res.in/handle/123456789/16443| Title: | Liquid phase oxidation of alkanes by tert-butyl hydroperoxide catalyzed by a manganese(III) pyridine amide complex |
| Authors: | Tembe, Gopal L Ganeshpure, Pralhad A |
| Issue Date: | May-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Oxidation of alkanes by tert-butyl hydroperoxide in acetonitrile solution at room temperature has been performed in the presence of catalytic amounts of [Mn(bpc)OAc]MeOH, where bpc=4, 5-dichloro-1, 2-bis(pyridine- 2- carboxamido)benzene. Cyclohexane, adamantane, toluene, ethylbenzene and cumene give corresponding oxygenated products in moderate to high yields. A mechanism predominantly involving radical chain pathway is proposed. |
| Page(s): | 611-613 |
| Appears in Collections: | IJC-B Vol.38B(05) [May 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(5) 611-613.pdf | 555.09 kB | Adobe PDF | View/Open |
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