Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/16514
Title: A short synthesis of trans-3-methoxy-4,5-methylenedioxycinnamaldehyde, a metabolite of Cassia grandis
Authors: Rajasekhar, Dodda
Subbaraju, Gottumukkala V
Issue Date: Jul-1999
Publisher: NISCAIR-CSIR, India
Abstract: Claisen-Schmidt reaction of 3-methoxy-4, 5-methy1cncdioxybenzaldchyde 2 with acetaldehyde affords the trans-3-methoxy-4, 5-methylenedioxycinnamaldehyde 1, a metabolite of Cassia grandis, in 12% yield. Compound 2 could also be converted into 1, via the reaction with triethyl phosphonoacetate followed by reduction with LAH and oxidation with MnO2 in 40% overall yield.
Page(s): 837-838
Appears in Collections:IJC-B Vol.38B(07) [July 1999]

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