Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/16580Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Singh, Manoj K | - |
| dc.contributor.author | Singh, Ram S | - |
| dc.contributor.author | Singh, Radhey M | - |
| dc.date.accessioned | 2013-03-29T11:22:15Z | - |
| dc.date.available | 2013-03-29T11:22:15Z | - |
| dc.date.issued | 1999-08 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/16580 | - |
| dc.description | 920-924 | en_US |
| dc.description.abstract | The reaction of methyl 3-arylamino-2-benzoylaminopropenoates 2 with phosphorus oxychloride in pyridine at 70°C for 30 min leads to the unexpected formation of N-aryl-N-bis-(5-oxo-2-phenyl-4, 5- dihydro-oxazol-4-ylmethylene) amines 4. In contrast, 4-arylaminomethylene-2-phenyl-2-oxazolin-5-ones 3 are obtained in only 2 min from compounds 2 under similar reaction conditions, which subsequently give compounds 4 on treatment with POCI3 in pyridine. A tentative mechanism to account the following conversion is suggested. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights | CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-B Vol.38B(08) [August 1999] | en_US |
| dc.title | Methyl 3-arylamino-2-benzoylaminopropenoates in the synthesis of 4-arylaminomethylene-2-phenyl-2-oxazolin-5-ones: Unexpected formation of bis-oxazolones | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-B Vol.38B(08) [August 1999] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(8) 920-924.pdf | 819.09 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.