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http://nopr.niscpr.res.in/handle/123456789/16590| Title: | Selective conversion of nitriles to amides by Amberlyst A-26 supported hydroperoxide |
| Authors: | Lakouraj, M Mansour Bahrami, K |
| Issue Date: | Aug-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A mild, efficient and selective conversion of nitriles to amides is achieved by employing Amberlyst A-26 supported hydroperoxide, which is prepared in situ from hydrogen peroxide and Amberlyst A-26 (OH- form). Nitriles and dinitriles are transformed to their corresponding amides and diamides, respectively. Reactions proceed within 0.5-5 hr upon addition of a catalytic amount of Amberlyst A 26(OH-) to a methanolic solution of nitrile and hydrogen peroxide (35%), at room temperature. |
| Page(s): | 974-975 |
| Appears in Collections: | IJC-B Vol.38B(08) [August 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(8) 974-975.pdf | 467.59 kB | Adobe PDF | View/Open |
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