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dc.contributor.authorJanardhana, Chelli-
dc.contributor.authorRao, S Jagadeeswara-
dc.contributor.authorVenkatesh, V-
dc.contributor.authorKiran, J Sai-
dc.contributor.authorSathish, R Sai-
dc.date.accessioned2013-05-13T05:53:25Z-
dc.date.available2013-05-13T05:53:25Z-
dc.date.issued2005-01-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/18052-
dc.description76-79en_US
dc.description.abstractPhotolysis of ([Co(tetraen)Cl] (ClO4)2 and [Co(tetraen)NO2] (ClO4)2  chelates in 0.1 M aq HClO4 , methanol and acetonitrile media yields cobalt(II) chelates. Oxygenation reactions of cobalt(II) bound to tetraen, {N-(2-aminoethyl)-N1- [2-[(2- aminoethyl)amino]ethyl]-1 ,2-ethanediamine)  have been studied by continuous and flash photolysis techniques. Quantum yields and excited state deactivation pathways for cobalt(III) – amine complexes have been investigated and a scheme for the excited state processes suggested. A comparison of the quantum yields in different solvent media indicates the role of solvent on the quantum yield for the photoredox process.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.44A(01) [January 2005]en_US
dc.titleOxygenation reactions of cobalt(II) tetraen chelates generated on flash photolysis and continuous photolysis of cobalt(III) complexes in different solventsen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.44A(01) [January 2005]

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