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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Chimatadar, S A | - |
| dc.contributor.author | Koujalagi, S B | - |
| dc.contributor.author | Nandibewoor, S T | - |
| dc.date.accessioned | 2013-05-17T08:59:12Z | - |
| dc.date.available | 2013-05-17T08:59:12Z | - |
| dc.date.issued | 2002-02 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/18222 | - |
| dc.description | 316-320 | en_US |
| dc.description.abstract | Kinetics of oxidation of mercury(I) by iron(III)-2,2'-bipyridyl in the presence of microamounts of palladium(II) has been studied spectrophotometrically in aqueous nitric acid and methanol media. The reaction exhibits first order each in [iron(III)-2,2ʹ-bipyridyl ] and [palladium(II)] and zero order in [mercury(I). Increase in [HNO3] decreases the reaction rate. Added products do not have any significant effect on the reaction rate. A suitable reaction mechanism is proposed and the reaction constants of the different steps involved have been evaluated. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.41A(02) [February 2002] | en_US |
| dc.title | Kinetics of palladium(II) catalysed oxidation of mercury(I) by iron(III)-2,2'-bipyridyl complex | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.41A(02) [February 2002] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(2) 316-320.pdf | 1.07 MB | Adobe PDF | View/Open |
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