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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Gosain, Jaya | - |
| dc.contributor.author | Sharma, Pradeep K | - |
| dc.date.accessioned | 2013-05-17T09:02:49Z | - |
| dc.date.available | 2013-05-17T09:02:49Z | - |
| dc.date.issued | 2002-02 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/18223 | - |
| dc.description | 321-324 | en_US |
| dc.description.abstract | Kinetics and mechanism of oxidation of formic and oxalic acids by tetrabutylammonium tribromide (TBATB) have been studied in 1:1 (v/v) acetic acid-water solutions. The main product of oxidation is carbon dioxide. The reaction is first order with respect to TBATB. Michaelis-Menten type of kinetics has been observed with respect to the reductants. The oxidation of α deuterioformic acid exhibits a substantial primary kinetic isotope effect (kH/kD = 5.85 at 298 K). The reaction has been studied in solvents of different compositions of acetic acid and water. The solvent composition effect has been analysed using Grunwald-Winstein equation. Suitable mechanisms have been proposed. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.41A(02) [February 2002] | en_US |
| dc.title | Kinetics and mechanism of the oxidation of formic and oxalic acids by tetrabutylammonium tribromide | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.41A(02) [February 2002] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(2) 321-324.pdf | 858.04 kB | Adobe PDF | View/Open |
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