Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/18258
Title: Mixed-ligand complexes of cobalt(II) and nickel(II) with 2-sulphanylbenzothiazolate and (N,N) chelating ligands
Authors: Singh, Nanhai
Gupta, Sushmita
Issue Date: Apr-2002
Publisher: NISCAIR-CSIR, India
Abstract: A series of new, neutral [M(C7H4NS2)2(phen)] and salt-like [M(N-N3]( C7H4NS2)2, mixed-ligand complexes {M=Co(II) or Ni(II); C7H4NS2=2-sulphanylbenzothiazolate, N-N= 1,10-phenanthroline (phen) or ethylenediamine (en)} have been prepared and characterized by elemental analysis, IR, UV-visible and conductivity techniques. All the compounds exhibit σrt in the 10-13-10-6 S cm-1 range. Temperature dependence (303-373 K) of the compressed pellet conductivity together with the band gaps in the 0.26-2.87 eV range show semiconducting behaviour of the compounds.
Page(s): 771-773
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections: IJC-A Vol.41A(04) [April 2002]

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