Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/18259| Title: | Synthesis, characterization and redox behaviour of camphorquinone monooximate complexes of osmium(II), -(III) and -(IV) |
| Authors: | Bose, Doyel Rahaman, Hafijur Das, Pradyut Kumar Sinha, Chittaranjan Ghosh, Barindra Kumar |
| Issue Date: | Apr-2002 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A group of dihalogenobis complexes of the type [OsX2(HA)(A)] (1) and mixed-tris chelates of types [Os(A)(L)2] - CIO4.H2O (2), Os(A)(Q)2 (3) and [Os(A)(Q)2]CIO4.H2O (4) [where X=CI or Br; HA=camphor-quinone monooxime; L = 2-(arylazo)pyridines and HQ=quinolin-8-ol and its derivative] have been prepared by distinctly different synthetic routes and characterized by microanalytical, IR, EPR, UV-Vis and electrochemical results. Reversible/nearly- reversible osmium(III)-osmium(II) and osmium(IV)-osmium(III) couples are invariably seen in all the complexes. |
| Page(s): | 774-779 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.41A(04) [April 2002] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(4) 774-779.pdf | 1.45 MB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.