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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Srivastava, Amar | - |
| dc.contributor.author | Shrimal, A K | - |
| dc.date.accessioned | 2013-05-20T09:13:51Z | - |
| dc.date.available | 2013-05-20T09:13:51Z | - |
| dc.date.issued | 2002-04 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/18261 | - |
| dc.description | 785-790 | en_US |
| dc.description.abstract | The Schiff bases (SB) viz., 1,2-bis(4-methylbenzylideneimine) propane (SB1), l ,2-bis(4-methoxybenzylideneimine) propane (SB2), 1,2-bis(4-N,N-dimethylaminobenzylideneimine) propane (SB3), 1,2-bis( 4-methylacetophenoneimine)propane (SB4) and 1,2-bis(4-methoxyacetophenoneimine)propane (SB5) react with tungsten hexacarbonyl in xylene to give cis-disubstituted derivatives, cis-[(SB)W(CO)4]. Schiff base bridged dinuclear [(Ph3E)(CO)4W(µ-SB)W(CO)4(Ph3E)] derivatives have been synthesized with [(Ph3E)(CO)5] (E = P or As). Cis[(SB)W(CO)4] yielded [(S8)W(CO)3X2] when reacted with X2(X = Br or I) but produced CO free product [(SB)WCI4] after reaction with chlorine. The complexes have been characterized by elemental analysis, infrared and magnetic moment studies. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.41A(04) [April 2002] | en_US |
| dc.title | Schiff base derivatives of tungsten carbonyl | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.41A(04) [April 2002] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(4) 785-790.pdf | 1.25 MB | Adobe PDF | View/Open |
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