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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Jesudurai, D | - |
| dc.contributor.author | Vancheesan, S | - |
| dc.date.accessioned | 2013-05-20T11:03:31Z | - |
| dc.date.available | 2013-05-20T11:03:31Z | - |
| dc.date.issued | 2002-05 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/18277 | - |
| dc.description | 976-980 | en_US |
| dc.description.abstract | Two zero-valent metal carbonyl complexes fac -[M(CO)3(NI C)3] (where M = Mo, W; 3, 4; NIC = 3-HO2CC5H4N) have been synthesized and characterized by elemental and thermal analyses (TGA, EGA), IR and powder X-ray diffraction (XRD) spectroscopic techniques. The IR spectrum of complex 3 exhibits three CO stretching bands and 4 shows two CO stretching bands in addition to a carboxylic-carbonyl stretching band. The possibility of fac / mer isomerization in complex 3 has been studied by IR spectroscopy in various solvents. Elemental, and mass spectrometric data are consistent with the formulae of the title complexes. The powder X-ray diffractogram of complexes 3 and 4 exhibit similar pattern suggesting the same geometry. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.41A(05) [May 2002] | en_US |
| dc.title | Synthesis and characterization of nicotinic acid coordinated metal carbonyl complexes | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.41A(05) [May 2002] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(5) 976-980.pdf | 1.19 MB | Adobe PDF | View/Open |
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