Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/18333
Title: Hydrodechlorination of dichlorodifluoromethane over novel CrF3 supported palladium catalysts
Authors: Cao, Yu Cai
Jiang, Xuan Zhen
Issue Date: Aug-2002
Publisher: NISCAIR-CSIR, India
Abstract: Novel CrF3 supported palladium catalysts have been prepared through two different precursors i.e. dichlorobistriphenylphosphine palladium (DCTPPP) and PdCl2 for the hydrodechlorination of CFC-12. These catalysts exhibited improved catalytic activities in hydrodechlorination of CFC-12 as compared with conventional Pd/γ-Al2O3. Particularly, high selectivities (~81%) of CH2F2 formation have been achieved over DCTPPP/CrF3. The improved catalytic performance may be attributed to the nature of support CrF3 and the formation of fine palladium particles in the catalysts.
Page(s): 1607-1611
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.41A(08) [August 2002]

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