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http://nopr.niscpr.res.in/handle/123456789/18460| Title: | Preparation and properties of novel heterobimetallic glycolate derivatives of titanium and zirconium |
| Authors: | Sharma, Maneesh K Singh, Anirudh Mehrotra, Ram C |
| Issue Date: | Mar-2001 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reaction in 1:3 molar ratio of titanium and zirconium isopropoxides with glycols (2,5-dimethyl hexane- 2,5-diol/2,3-dimethyl butane-2,3-diol) in benzene under refluxing conditions afford soluble aggregates of the composition [M(O-G-O)(O-G-OH)2] (M=Ti, Zr; G = (CH3)2CCH2CH2C(CH3)2 or (CH3)2CC(CH3 )2) These on treatment with isopropoxides of other metals (eg; Al, Ti, Nb and Ta) yield heterobimetallic isopropoxide-glycolate derivatives which have been characterized by elemental analyses, spectroscopic (IR, NMR (1H, 13C, 27AL)) data and molecular weight measurements. |
| Page(s): | 236-240 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.40A(03) [March 2001] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 40A(3) 236-240.pdf | 912.91 kB | Adobe PDF | View/Open |
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