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http://nopr.niscpr.res.in/handle/123456789/18497| Title: | Synthesis of the binuclear copper(I) complex containing bis(diphenylphosphino) ethane |
| Authors: | Dongmei, Wang Ruina, Yang Yingfan, Liu Douman, Jin |
| Issue Date: | Apr-2001 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | At room temperature, the reaction of metallic copper powder with 2-thenoyltritluoroacetone and bis (diphenylphosphino)ethane gives the binuclear copper(I) complex, [Cu(dppe)(tfac)]2. The complex has been characterized by physico-chemical and spectroscopic methods. X-Ray structure of the title complex shows that 2-thenoyltritluoroacetone behaves as a chelating ligand and dppe coordinates as bridging bidentate ligand to CuI atoms in the newly prepared copperI complex. The crystal is monoclinic, space group C2/c, with cell parameters a= 25.215(6); b= 15.304(9), c= 18.851 (6) Å. β= 107.20(3)o , Z= 4, V= 6949.0(2) Å3, R=0.06682, Rw=0.07326. |
| Page(s): | 415-418 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.40A(04) [April 2001] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 40A(4) 415-418.pdf | 878.93 kB | Adobe PDF | View/Open |
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