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http://nopr.niscpr.res.in/handle/123456789/18532| Title: | Reduction of carboxylato-bound chromium(IV) with hydroxylamine |
| Authors: | Kumar, Manjuri Ghosh, Sanchita P Koley, Aditya P Ghosh, Manik C |
| Issue Date: | Aug-2001 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Aqueous chromium(IV), stabilized through ligation by 2-ethyl-2-hydroxybutanoate ion, undergo facile reduction with hydroxylamine. Cr(IV) forms a precursor complex with NH30H+ (Kc = 30 ± 7 M-1) and electron is transferred from NH3OH+ to Cr(IV) within this complex. This electron transfer process is inhibited by excess ligand anion, as well as by hydrogen ion. |
| Page(s): | 827-830 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.40A(08) [August 2001] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 40A(8) 827-830.pdf | 759.39 kB | Adobe PDF | View/Open |
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