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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | De, Rajib Lal | - |
| dc.contributor.author | Maiti, Kamales | - |
| dc.date.accessioned | 2013-05-31T06:25:53Z | - |
| dc.date.available | 2013-05-31T06:25:53Z | - |
| dc.date.issued | 2001-10 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/18585 | - |
| dc.description | 1097-1100 | en_US |
| dc.description.abstract | The compounds (π-CpCo)3(CO)2PPh (1), (π-CpCo)3(CO) (PPh)2 (2) and (π-CpCo)3(CO)PCl (3) have been isolated from the reaction of dichlorophenylphosphine, PPhCl2 and trichloro- phosphine, PC13 respectively with π-cyclopentadienylcobaltdi- carbonyl, π-CpCo(CO)2. Decarbonylated products, (π-CpCo)3 (μ-CO)PPh, (4), (π-CpCo)3 (PPh)2 (5) and (π-CpCo)3 (μ-CO)P, (6) are formed on reactions of (1), (2) and (3) respectively with PPh3. The reactions between Fe3 (CO)12 and (2) or (3) stabilises (π-CpCo)2Fe(CO)4 (PPh)2 (7) or (π-CpCo)3Fe (CO)5PCl (8). The characteristics of the products have been ascertained by analytical and spectroscopic measurements. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.40A(10) [October 2001] | en_US |
| dc.title | Reactivity of π-cyclopentadienyl cobalt dicarbonyl with free phosphines—Isolation and properties of phosphorus bridged clusters | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.40A(10) [October 2001] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 40A(10) 1097-1100.pdf | 1.01 MB | Adobe PDF | View/Open |
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