Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/19949
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dc.contributor.authorRoy, Sukhendu-
dc.contributor.authorChakrabarty, Kuheli-
dc.contributor.authorMondal, Nityagopal-
dc.contributor.authorDas, Gourab Kanti-
dc.date.accessioned2013-07-22T06:53:30Z-
dc.date.available2013-07-22T06:53:30Z-
dc.date.issued2006-01-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/19949-
dc.description45-50en_US
dc.description.abstractInvestigation on the transition structure of the ene reaction between propyne and forma ldehyde reveals that negative electrostatic potential is generated around the carbonyl oxygen and acetylenic group. The generated electrostatic potential controls the orientation of the oxygenated substituent present on the forming cyclohexane ring in ene cyclisation. Data from the study of mono substituted transition structures have been used to rationalize the stereoselectivity of an ene cyclisation with poly oxygenated substituents.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.45A(01) [January 2006]en_US
dc.titleEffect of electrostatic potential of transition state on the stereoselectivity in ene cyclisation: A theoretical studyen_US
dc.typeArticleen_US
Appears in Collections: IJC-A Vol.45A(01) [January 2006]

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