Effect of side arm chain length of redox ionophores on uptake of some metal ions

Awasthy, Anubhuti; Bhatnagar, Mamta; Joshi, Nidhi; Sharma, Uma

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Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/19991

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DC Field	Value	Language
dc.contributor.author	Awasthy, Anubhuti	-
dc.contributor.author	Bhatnagar, Mamta	-
dc.contributor.author	Joshi, Nidhi	-
dc.contributor.author	Sharma, Uma	-
dc.date.accessioned	2013-07-22T10:00:51Z	-
dc.date.available	2013-07-22T10:00:51Z	-
dc.date.issued	2006-05	-
dc.identifier.issn	0975-0975(Online); 0376-4710(Print)	-
dc.identifier.uri	http://hdl.handle.net/123456789/19991	-
dc.description	1170-1172	en_US
dc.description.abstract	Synthesis of redox switched ionophores 1-[1-anthraquinonyloxy) 3, 6 dioxaoctane-8-methane (A₁) and 1-[1-anthraquinonyloxy] 3 oxapentane-5-methane (A₂) has been reported. These ionophores have been used as carriers in liquid membrane transport and extraction studies of alkali and alkaline earth metal ions. The sequence of metal ions extracted and transported in oxidised and reduced state by ionophore A₁ is: Ca²⁺>K⁺>Li⁺>Mg²⁺ and Li⁺>K⁺>Ca²⁺>Mg²⁺ respectively. The order of ex traction and transport of metal ions with respect to ionophore A₂is Li⁺>K⁺>Ca²⁺ and Ca²⁺>K⁺>Li⁺ respectively. Ionophore A₁ is selective for Ca²⁺ while ionophore A₂ is selective for Li⁺ions. This selectivity may be used in ion selective electrode and redox switch able devices.	en_US
dc.language.iso	en_US	en_US
dc.publisher	NISCAIR-CSIR, India	en_US
dc.relation.ispartofseries	Int. Cl.⁸ C07C59/00; G01N	en_US
dc.rights	CC Attribution-Noncommercial-No Derivative Works 2.5 India	en_US
dc.source	IJC-A Vol.45A(05) [May 2006]	en_US
dc.title	Effect of side arm chain length of redox ionophores on uptake of some metal ions	en_US
dc.type	Article	en_US
Appears in Collections:	IJC-A Vol.45A(05) [May 2006]

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