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http://nopr.niscpr.res.in/handle/123456789/19996| Title: | Structural diversity in supramolecular architectures of Mn(II) through non-covalent interactions |
| Authors: | Ghosh, Ananta Kumar Ghoshal, Debajyoti Drew, Michael G B Chaudhuri, Nirmalendu Ray |
| Issue Date: | Jun-2006 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int. Cl.8 C07F 13/00 |
| Abstract: | Two mononuclear complexes of manganese(II), [Mn(OCN)2(phen)2] 1 and [Mn (NCO)2(bpy)2] 2 [1,10-phenanthroline (phen): 2,2'-bipyridine (bpy)], have been synthesized and characterized by single crystal X-ray analysis, infra-red spectroscopy and magnetic studies. The coordination structure of complex 2 is already reported. The cyanate anions are pendent in both the complexes. In 1, cyanate anion links manganese(II) through O-atom, whereas in 2 it coordinates through N-atom. The mononuclear fragments of 1 are built up to a supramolceular lamellar 3D architecture by π-π interactions only. On the other hand, mononuclear fragments of 2 are assembled to a 2D supramolecular brick-wall architecture by C-H¨ interactions. |
| Page(s): | 1351-1355 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.45A(06) [June 2006] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 45A(6) 1351-1355.pdf | 1.11 MB | Adobe PDF | View/Open |
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